Murciano also appeared in Enterprise episode "Fusion", where he portrayed the Vulcan, Tolaris, and in the music video "Yes We Can."

Aside from acting Murciano was the executive producer for the made-for-TV youth drama A Separate Place.

1. "You get to a point when you're bored of trying to make life good and beautiful for yourself, and you want to start doing it for somebody else. I can't wait to do that." — Enrique Murciano on life with someone else
2. "I believe in giving directly. If I'm at a red light and there's a guy who went to war, who's homeless, I give more than a dollar at that point. A kid is sick, and I know about it? I take care of him. It's much more of a hands-on approach, stuff that doesn't go noticed but stuff that I know I did. If you're constantly dancing the dance of life, it keeps you very present." — Enrique Murciano on giving to others
3. "When I moved to L.A., my first agent suggested I change my name to Rick Mercer; it's close to Enrique Murciano in a way. But I'm very proud of who I am, and I'm very proud of Latinos--not just Cubans, but all Latinos." — Enrique Murciano on moving to Los Angeles
4. "I mix garlic, salt and spices. Every dish ends up with a Cuban twist to it, a little-cha-cha with every meal." — Enrique Murciano on cooking