Charm School with Ricki Lake was the third in the Charm School series. The girls were cast from the Rock of Love Bus and Real Chance of Love. Sharon Osbourne is no longer host, with Ricki Lake taking her place. The girls volunteered their time senior citizen centers, animal shelters and took a trip to New Orleans to help rebuild homes due to the destruction of Hurricane Katrina.

Each week the contestants focus on one lesson and then are tested on it. Any contestant who fails the challenges of Charm School or disrupts the house faces the chance of being expelled. One contestant will be eliminated each week, with the host Riki Lake and the deans having the only say in which contestant leaves. The winner will hold the title of "Charm School Queen" and take home the grand prize of $100,000.

• Ashley - Finalist
• Brittanya - Eliminated
• Marcia - Finalist
• Bay Bay Bay - Eliminated
• Bubbles - Eliminated
• K.O. - Eliminated
• Risky - Winner
• Natasha - Eliminated
• Brittaney Starr - Eliminated
• Farrah - quit
• So Hood - quit
• Gia - Eliminated
• Ki Ki - Eliminated
• Beverly - asked to leave