I think you would click on History, then show all history. Works for me!
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go to Start->Run and type in/copy and paste
C:\Documents and Settings\Administrator\Local Settings\Application Data\Mozilla\Firefox\Profiles\4krz7144.default\Cache

If that doesn't work for you, you can view the actually directory location by opening a new Firefox window/tab and typing in

about:cache

and looking for the path file.
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check your download folder in MyDocument folder or click on Tool in menubar and then Downloads or CRT+J
Source(s):
my experience

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if u want to access temporary files stored by mozilla firefox you can have them by entering "about:cache" in the address bar..
this will display window with following text...

Memory cache device

Number of entries: 73
Maximum storage size: 18432 KiB
Storage in use: 202 KiB
Inactive storage: 202 KiB

List Cache Entries
Disk cache device

Number of entries: 1370
Maximum storage size: 51200 KiB
Storage in use: 13623 KiB
Cache Directory: C:\Documents and Settings\Wel-Come\Local Settings\Application Data\Mozilla\Firefox\Profiles\o60mnuqk.default\Cache

List Cache Entries
Offline cache device

Number of entries: 0
Maximum storage size: 512000 KiB
Storage in use: 0 KiB
Cache Directory: C:\Documents and Settings\Wel-Come\Local Settings\Application Data\Mozilla\Firefox\Profiles\o60mnuqk.default\OfflineCache

List Cache Entries

After that click on "list cache entries" under "disk cache device"
it will list u all entries stored on your disk..
you can access these files directly as these are configured as octet stream..
by using appropriate program......
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