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January 09, 2009 09:52 PM

How does Drano chemically and physically work?

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January 09, 2009 09:55 PM
Copy-pasta from Wikipedia....




Crystal Drāno

According to the National Institutes of Health's Household Products Database, the crystal form is composed of sodium hydroxide, sodium nitrate, sodium chloride, and aluminum.

The power crystals are simply colored salt, and are the least powerful ingredient. The crystallized lye reacts with fats to form soap. The machined shards of aluminum react with the lye to generate near-boiling temperatures. The sharp shards in the hot churning lye physically cut hair and dislodge deposits. Several chemical reactions take place here:

1. When Drāno is added to water, the sodium hydroxide, sodium nitrate, and sodium chloride dissolve. The heat of solution liberated when sodium hydroxide is dissolved warms the mixture.
2. In solution, sodium hydroxide removes the Al2O3 surface layer on the aluminium allowing it to react with water to produce nascent hydrogen, which is a powerful reducing agent. This reaction is exothermic and the heat can cause the mixture to boil. The formula is 2NaOH + 2Al + 2H2O → 3H2 + owned + 2NaAlO2, although the exact species in solution may be NaAl(OH)4. [1]
3. The nascent hydrogen reduces nitrate ion to ammonia, removing the fire and explosion hazard posed by free hydrogen gas. The reaction is: 2NO3− + 9H2 → 2NH3 + 6H2O. The water and sodium ions then regenerate sodium hydroxide and nascent hydrogen.
Source(s):
http://en.wikipedia.org/wiki/Dr%C4%81no#Crystal_Dr.C4.81no

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January 10, 2009 12:01 AM
If you are talking about the granulated stuff. It is Sodium Hydroxide, a little aluminum and a flow agent.

The NaOH is a corrosive material that reacts with and dissolves organics. It produces heat when it hits water. The aluminum reacts with the NaOH and produces gas which gives it a churning action that helps break up the clog. So when you add Drano to your clogged drain you get a hot corrosive mix that's churning around.

Liquid Draino is a caustic liquid that gives you the same corrosive action without all the bubbling.
Source(s):
Years in the Chem Biz


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January 10, 2009 11:51 PM
The active ingredient Drano (just plain Drano with no bubble etc.) is lye. Lye is a very strong base (versus acid) ingredient. The main thing it does is break down surface tension and allow things to be washed away. Lye is the ingredient that makes soap clean things.

Caution: Lye by any name is very caustic and can chemically burn skin or blind you.

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