Howdy, I do not find anything about a star getting a key to the slime volcano. I did find this bit of info.

Orlando Bloom got the night's biggest slimming honor.

Hope this helps some!
Source(s):
http://www.popsugar.com/1512583

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the jonas brothers had they key. 'the key of g' as in a musical key...they sang part of lovebug but they changed the lyrics a bit... "now i'm speechless over the edge i'm just breathless i never thought that i'd get this slime time again" something like that, and then the volcano exploded sliming the audience and the jonas brothers and the rock.

here is a video of it:
Source(s):
kids choice awards 2009, youtube

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The key wasnt actually a key.
Dwane Johnson did a traditional hawaiian dance, with traditional hawaiian dancers. It was amazing. I love those kinds of dances.

The "slime gods" were happy, and out comes jonas brothers. they said that they didnt have a key. And one of the Jo Bros said only key we know is the key we sing in. And one said hey, lets sing in key G, as in for Green. And they started sing Love like this (?) song, and slime came from EVERYWHERE! it was cute!
Source(s):
I watched it, and recorded it.

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