Here are a few tips I've learned for getting going on those rough Mondays:

1. Music: Whether it's programming your alarm clock to wake you up to a little Marilyn Manson, or rocking out to AC/DC in your car on the way to work, some good, loud music is always a good way to get "pumped."

2. Exercise: A short burst of exercise early in the morning is a good way to get your blood flowing and tells your body that it's time to get up and move. A short run around the block, a few situps, or a short bike ride can definitely help. Grab your ipod and combine it with music for an extra burst.

3. Coffee. Nuff said. None of this decaf, soy latte, chai mystic tea Shenanigans. Just straight black coffee. Does the trick every time.
Source(s):
Personal Experience

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Absolutely agree with the previous answerers on the importance of exercise (taking a quick walk around the block is great, and you can stop by a coffee shop for a shot of java on your way home). But the most important thing you can do to stop feeling sleepy on Monday is to get enough sleep! Go to bed on time on Sunday night. In fact, make sure you go to bed and get up at the same times each day, no matter if it's a weekend or weekday. This will set your body clock and let you feel rested when you wake up every day!
Source(s):
http://women.webmd.com/guide/insomnia-tips

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Usually exercise is the best way to kick yourself awake. Far more healthy than any sort of chemical stimulate.
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